
Monday,
September 22, 2008 @ 4:00
p.m.
Louise Foucar Marshall Building Room 531
Avener
Vengosh, Nicholas School
of
Environment
Duke University
vengosh@duke.edu
"High
Radioactivity in Fossil Groundwater in the Middle East: A New Challenge for
Water Management"
The Nubian sandstones
basins of the Middle East and northeastern Africa host several important aquifers with high-quality,
yet fossil, groundwater that is becoming an essential water source in the
region. In Jordan, fossil
groundwater from the Paleozoic Disi (Saq) aquifer is part of a new large-scale
water project in which water will be transferred to the capital Amman to compensate water shortage in Jordan.
In my talk I will present the geochemical (major and trace elements),
radium, strontium, oxygen, and hydrogen isotope compositions of groundwater from
the Disi aquifer in southern and central
Jordan. The radium activities in the
low-saline groundwater from the Rum
Group are high and largely exceed international drinking water standards. The
228Ra/226Ra ratios in groundwater from the confined zone
(2.8) are higher than
sandstone rocks (~1.6), while their 224Ra/223Ra ratios
(32-25) are consistent with theoretical 224Ra/223Ra ratios
emitted by recoil from sandstone rocks. The high ratios of the short-lived
224Ra and 223Ra to the long-lived 226Ra and 228Ra
isotopes indicate that Ra mobilization is controlled by recoil process from the
aquifer solids combined with rapid Ra adsorption. Based on compilation of radium
and radon data from worldwide groundwater and sandstone rocks, we propose that
radium levels in groundwater resources are depend on the contents of efficient
radium scavenging minerals (e.g., clays, Fe- and Mn-oxides) in sandstone
aquifers that control Ra retardation.
These findings could have
implications for high radium anomalies in low-saline groundwater from similar
Nubian Sandstone basins in the region and exacerbate the already severe water
crisis in the Middle East.